Dichlorido(6-methyl-2,2′-bipyridine-κ2 N,N′)zinc(II)
نویسندگان
چکیده
In the mol-ecule of the title compound, [ZnCl(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 6-methyl-2,2'-bipyridine ligand and by two Cl atoms. There are π-π contacts between the pyridine ring and the five-membered ring, and also between the pyridine rings, [centroid-centroid distances = 3.685 (3) and 3.757 (3) Å, respectively].
منابع مشابه
Dichlorido(6-methyl-2,2′-bipyridine-κ2 N,N′)mercury(II)
In the mol-ecule of the title compound, [HgCl(2)(C(11)H(10)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two Cl atoms. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.9758 (5) Å].
متن کاملDichlorido(6-methyl-2,2′-bipyridine-κ2 N,N′)cobalt(II)
In the title compound, [CoCl(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.745 (3) Å] are present in the crystal.
متن کاملDichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc(II)
The asymmetric unit of the title compound, [ZnCl(2)(C(12)H(12)N(2))], contains two independent mol-ecules. The Zn(II) atoms are four-coordinated in distorted tetra-hedral configurations by two N atoms from 5,5'-dimethyl-2,2'-bipyridine and two terminal Cl atoms. In the crystal structure, inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules. There are C-H⋯π contacts between the methyl group...
متن کاملDibromido(6-methyl-2,2′-bipyridine-κ2 N,N′)zinc(II)
In the title compound, [ZnBr(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Br atoms. Weak inter-molecular C-H⋯Br hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.763 (5) and 3.835 (6) Å] contribute to crystal-packing...
متن کامل(2,2′-Bipyridine-κ2 N,N′)bis(4-methylbenzoato-κ2 O,O′)zinc(II)
In the title compound, [Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by four O atoms from two chelating 4-methyl-benzoate ligands and two N atoms from a 2,2'-bipyridine ligand, displaying a disordered octahedral geometry. C-H⋯O hydrogen bonds connect the complex mol-ecules into a three-dimensional supra-molecular structure.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008